Just downloaded this earlier and followed step by step and it did not work. I don't have my W3 installed to my C drive, though I directed the executable to where I did have it installed, for whatever reason when I launch the game, no matter the combination of Shift/Home and F2 the shader option never pops up, game looks like the default version, nothing changed or modified. Update, was able to fix it, thanks.
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?1. In order to activate the ReShade console you need to press the "Home" key or“Shift + F2” combination of keys.