I have the Steam version and Printscn key doesn't work for me. I push F12. It creates a .bmp file in the Skyrim folder. Go into the Program Files (x86) folder (I have Win7) and look for the STEAM folder. Left click to open it and look for the Steamapps folder. Left click that and look for the Common folder. It's going to be a .bmp file inside the Common folder.
I put that line in my skyrimprefs.ini. I then took a screenshot by pressing print screen and no bmp files were in my Skyrim folder. Am I doing something wrong?
*edit. okay its got something to do with enbseries. I pressed printscreen about a 20 times and i managed to get about 5 shots with filenames like enb2012_8_24_12_1_11.bmp
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Make sure you added the lines in Skyrim.ini and NOT in SkyrimPrefs.ini
I did that mistake at first... xD And its working now.
Thanks @Cohenat ">
*edit. okay its got something to do with enbseries. I pressed printscreen about a 20 times and i managed to get about 5 shots with filenames like enb2012_8_24_12_1_11.bmp