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Tl;dr: the alignment wheel is literally treated as a wheel behind the scenes. So when you're peak Lawful Good or Chaotic Evil or whatever, whenever you take a pure Good or Evil choice, the game has to shift your character towards the neutral end in order to reach peak Good/Evil.
I consider this dumb so this mod changes that:
Specifically, whenever you take a purely Good dialogue option:
If you are Chaotic or Lawful Good, the alignment shift change will be altered to either Chaotic Good or Lawful Good so you don't come at risk of shifting to Neutral Good.
Whenever you take a purely Evil dialogue option: If you are Chaotic or Lawful Evil, the alignment shift change will be altered to either Chaotic Evil or Lawful Evil so you don't come at risk of shifting to Neutral Evil.
Options that are specifically Neutral or Lawful or Chaotic will not be affected. How to install
Download and install Unity Mod Manager, make sure it is at least version 0.23.0
Run Unity Mod Manager and set it up to find Wrath of the Righteous
Download the Fix Alignment Shifts mod
Install the mod by dragging the zip file from step 5 into the Unity Mod Manager window under the Mods tab