Make sure that you copy "666_BetterRoadsVC.pak" file to "GTA Vice City - The Definitive Edition\Gameface\Content\Paks\~mods\ folder.
BTW maybe you named "~mods" folder as "mods" by mistake, it must contain the ~ in name. Or you might have actually copied it to My Documents folder which is a common mistake, it must be in actual game`s folder.
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Make sure that you copy "666_BetterRoadsVC.pak" file to "GTA Vice City - The Definitive Edition\Gameface\Content\Paks\~mods\ folder.
BTW maybe you named "~mods" folder as "mods" by mistake, it must contain the ~ in name.
Or you might have actually copied it to My Documents folder which is a common mistake, it must be in actual game`s folder.
Looks great imo.